docs: document base ffmpeg arguments passed before preset ffargs

Both the README and the man page now explain that the script always
passes -map 0, -map_metadata 0, -map_chapters 0, and -c copy to
ffmpeg before appending the preset's ffargs array. This context is
important for preset authors, who only need to override the streams
they intend to re-encode.

Also fix a minor blockquote rendering issue in the README (missing
blank line before the fenced code block in the PATH note).

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